JPS587406A - プロピレン重合体の製造法 - Google Patents
プロピレン重合体の製造法Info
- Publication number
- JPS587406A JPS587406A JP10530681A JP10530681A JPS587406A JP S587406 A JPS587406 A JP S587406A JP 10530681 A JP10530681 A JP 10530681A JP 10530681 A JP10530681 A JP 10530681A JP S587406 A JPS587406 A JP S587406A
- Authority
- JP
- Japan
- Prior art keywords
- propylene
- polymer
- weight
- molecular weight
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 229920001155 polypropylene Polymers 0.000 title description 14
- 229920000642 polymer Polymers 0.000 claims description 26
- 238000006116 polymerization reaction Methods 0.000 claims description 26
- 239000003054 catalyst Substances 0.000 claims description 22
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 19
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 19
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- 239000004711 α-olefin Substances 0.000 claims description 8
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 7
- 229920001384 propylene homopolymer Polymers 0.000 claims description 6
- -1 aluminum compound Chemical class 0.000 claims description 4
- 239000011949 solid catalyst Substances 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 241001164374 Calyx Species 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- 229920005606 polypropylene copolymer Polymers 0.000 claims 1
- 238000000465 moulding Methods 0.000 description 21
- 230000000052 comparative effect Effects 0.000 description 17
- 239000001257 hydrogen Substances 0.000 description 16
- 229910052739 hydrogen Inorganic materials 0.000 description 16
- 238000000034 method Methods 0.000 description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 12
- 239000007789 gas Substances 0.000 description 10
- 229920006158 high molecular weight polymer Polymers 0.000 description 10
- 241000251468 Actinopterygii Species 0.000 description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 9
- 239000005977 Ethylene Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 238000007665 sagging Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 5
- 230000003746 surface roughness Effects 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000000071 blow moulding Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000012456 homogeneous solution Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 150000002681 magnesium compounds Chemical class 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 description 1
- ODJQKYXPKWQWNK-UHFFFAOYSA-L 3-(2-carboxylatoethylsulfanyl)propanoate Chemical compound [O-]C(=O)CCSCCC([O-])=O ODJQKYXPKWQWNK-UHFFFAOYSA-L 0.000 description 1
- 241000251730 Chondrichthyes Species 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 241000755266 Kathetostoma giganteum Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 101100208721 Mus musculus Usp5 gene Proteins 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 208000037062 Polyps Diseases 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 241000270666 Testudines Species 0.000 description 1
- IPBVNPXQWQGGJP-UHFFFAOYSA-N acetic acid phenyl ester Natural products CC(=O)OC1=CC=CC=C1 IPBVNPXQWQGGJP-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- ZMXPNWBFRPIZFV-UHFFFAOYSA-M dipropylalumanylium;chloride Chemical compound [Cl-].CCC[Al+]CCC ZMXPNWBFRPIZFV-UHFFFAOYSA-M 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 210000000744 eyelid Anatomy 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- GAZIBGHLWYHBDT-UHFFFAOYSA-N n-propylpropan-1-amine;hydrochloride Chemical compound Cl.CCCNCCC GAZIBGHLWYHBDT-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229940049953 phenylacetate Drugs 0.000 description 1
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10530681A JPS587406A (ja) | 1981-07-06 | 1981-07-06 | プロピレン重合体の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10530681A JPS587406A (ja) | 1981-07-06 | 1981-07-06 | プロピレン重合体の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS587406A true JPS587406A (ja) | 1983-01-17 |
| JPH0323565B2 JPH0323565B2 (en]) | 1991-03-29 |
Family
ID=14404014
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10530681A Granted JPS587406A (ja) | 1981-07-06 | 1981-07-06 | プロピレン重合体の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS587406A (en]) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58173141A (ja) * | 1982-04-05 | 1983-10-12 | Showa Denko Kk | 押出し延伸用ポリプロピレン系樹脂組成物の製造方法 |
| US4950720A (en) * | 1988-04-29 | 1990-08-21 | Exxon Chemical Patents Inc. | Modified polypropylene, process for making and article made from the same |
| US5141994A (en) * | 1988-11-04 | 1992-08-25 | Sumitomo Chemical Co., Ltd. | Crystalline polypropylene and crystalline polypropylene composition |
| JP2003268172A (ja) * | 2002-03-13 | 2003-09-25 | Sumitomo Chem Co Ltd | ポリプロピレン系樹脂組成物 |
-
1981
- 1981-07-06 JP JP10530681A patent/JPS587406A/ja active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58173141A (ja) * | 1982-04-05 | 1983-10-12 | Showa Denko Kk | 押出し延伸用ポリプロピレン系樹脂組成物の製造方法 |
| US4950720A (en) * | 1988-04-29 | 1990-08-21 | Exxon Chemical Patents Inc. | Modified polypropylene, process for making and article made from the same |
| US5141994A (en) * | 1988-11-04 | 1992-08-25 | Sumitomo Chemical Co., Ltd. | Crystalline polypropylene and crystalline polypropylene composition |
| JP2003268172A (ja) * | 2002-03-13 | 2003-09-25 | Sumitomo Chem Co Ltd | ポリプロピレン系樹脂組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0323565B2 (en]) | 1991-03-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5362782A (en) | Polymer compositions | |
| AU605811B2 (en) | Process for producing crystalline vinyl aromatic polymers having mainly a sydiotactic structure | |
| KR960001217B1 (ko) | 고결정정 폴리프로필렌 및 이를 함유하는 고결정성 프로필렌-에틸렌 블록 고중합체 | |
| US5258464A (en) | Impact copolymer compositions | |
| US4550143A (en) | Composition comprising ethylene-based polymers | |
| EP0114391B1 (en) | Flexible propylene polymer | |
| EP0457455B1 (en) | Polymer compositions | |
| EP0698045A1 (en) | High melt strength polypropylene, continuous process for the production thereof, and molded article | |
| JPH06199928A (ja) | エチレン−プロピレンブロック共重合体の製造方法 | |
| DE60009012T2 (de) | Copolymer-Zusammensetzung basierend auf Propen | |
| JPS59172507A (ja) | ポリプロピレンの製造方法 | |
| JPH06182756A (ja) | 分子量の異なるエチレンポリマーの溶融混合方法 | |
| JPH08198913A (ja) | ポリプロピレンフイルム | |
| JPS587406A (ja) | プロピレン重合体の製造法 | |
| JP2882237B2 (ja) | ポリプロピレンランダム共重合体及びそのフィルム | |
| JPH07149974A (ja) | 異なったプロピレンポリマーの高流動性ブレンド | |
| JPH0348214B2 (en]) | ||
| JPH0326203B2 (en]) | ||
| HU181967B (en) | Process for producing propylene-ethylene aulk copolymeres | |
| JPS62209153A (ja) | 樹脂組成物 | |
| JP4590148B2 (ja) | ポリエチレン樹脂組成物 | |
| JPH0148939B2 (en]) | ||
| JP3440798B2 (ja) | レトルト食品包装用フィルム | |
| KR20190062035A (ko) | 빠른 결정화 속도와 우수한 내충격성을 갖는 중공성형용 폴리에틸렌 수지 | |
| JPH0377806B2 (en]) |